I doubt a private sector union at Amazon would have the power to get such a deal.
According to an arbitration decision in 2010, it sounds like the MTA strategically withdrew an OPTO clause specifically to get less hammered by labor on other issues during arbitration: https://www.scribd.com/doc/18552062/The-M-T-A-and-T-W-U-Arbi...
I doubt a private sector union at Amazon would have the power to get such a deal.